Publications

2016

  1. Life Cycle Assessment of Photodegradable Polymeric Material Derived from Renewable Bioresources. Isola, C.;, Sieverding, H. L.; Raghunathan, R.; Sibi, M. P.; Webster, D. C.; Sivaguru, J.; Stone, J. J. Journal of Cleaner Production, Under Revision
  2. Synthesis of Silicon Quantum Dots using Cyclohexasilane (Si6H12). Guruvenkat, S.; Hoey, J. M.; Anderson, K. J.; Frohlich, M. T.; Krishnan, R.; Sivaguru, J.; Sibi, M. P.; Boudjouk, P. J. of Materials Chemistry: Materials for Optical and Electronic Devices, 2016, 4, 8206-8213.
  3. Synthesis and Characterization of Polyurethane Networks Derived from Soybean Oil-Based Cyclic Carbonates and Bio-Based Diamines. Samanta, S.; Sermadurai, S.; Bahr, J.; Wicramaratne, D. S.; Sibi, M. P.; Chisholm, B. J. ACS Sustainable Chemistry & Engineering 2016,
  4. Oraganophotocatalysis: Insights into the Mechanistic Aspects of Thiourea-Mediated intermolecular [2+2]-Photocycloaddition. Vallavogu, N.; Sermadurai, S.; Pemberton, B.; Jockusch, S.; Sibi, M. P.; Sivaguru, J. Angew. Chem. Int. 2016, 55, 5446-5451. Frontispiece article
  5. Evaluating thiourea/urea catalyst for enantioselective 6p-photocyclization of acrylanilide. Raghunathan, R.; Steffen Jockusch, S.; Sibi, M. P.; Sivaguru, J. J. Photochem. Photobiol. A. 2016, in early view.

2015

  1. An alternative to alkyds: Novel biobased polymers for coatings applications. Kalita, H.; Kalita, D.; Sibi, M. P.; Chisholm, Bret J.  European Coatings Journal 2015, (6), 26-29.
  2. Novel bio-based polymers for coating applications. Chisholm, Bret J.; Kalita, Harjoyti; Kalita, Deep; Alam, Samim; Chernykh, Andrey; Tarnavchyk, Ihor; Bahr, James; Samanta, Satyabrata; Jayasooriyama, Anurad; Fernando, Shashi; Proceedings of the International Waterborne, High-Solids, and Powder Coatings Symposium (2015), 42nd, 18-32.
  3. Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations. Kumarasamy, E.; Raghunathan, R.; Sibi, M. P.; Sivaguru, J. Chem. Rev. 2015, 15(20), 11239-11300. DOI: 10.1021/acs.chemrev.5b00136
  4. Linear Polyester Synthesized from Furfural-based Monomer by Photoreaction in Sunlight. Wang, Z.; Kastern, B.; Randazzo, K.; Ugrinov, A.; Butz, J.; Seals, D.; Sibi, M. P.; Chu, Q. R. Green Chemistry, 2015, 17, 4720-4724. DOI:10.1039/C5GC01783A.  Cover Article
  5. Catalytic Kinetic Resolution of Biaryl Compounds. G.; Sibi, M. P. Chem. Eur. J. 21, 11644-11657. DOI:10.1002/chem.201500869. Frontispiece article
  6. Structural and Solubility Parameter Correlations of Gelation Abilities for Dihydroxylated Derivatives of Long-chained, Naturally-occurring Fatty Acids. Zhang, M.; Selvakumar, S.; Zhang, X.; Sibi, M. P.; Weiss, R. G. Chem. Eur. J. 2015, 21(23), 8530-8543. DOI:10.1002/chem.20150009
  7. Novel Biobased Polymers for Coatings Applications. Kalita, H.; Alam, S.; Kalita, D.; Chernykh, A.; Tarnavchyk, I.; Bahr, J.; Samanta, S.; Jayasooriyamu, A.; Fernando, S.; Selvakumar, S.; Wickramaratne, D. S.; Sibi, M. P.; Chisholm, B. J. Journal of Coatings Technology and Research 2015, 12, 633-646. JCTR-D-14-00282R1
  8. Characterization of Brønsted Acid-Base Complexes by 19F DOSY. Subramanian, H.; Jasperse, C. P.; Sibi, M. P. Lett. 2015, 17, 1429-1432. DOI: 10.1021/acs.orglett.5b00297
  9. Lewis Acid Mediated Diastereoselective Intermolecular Radical Addition/Trapping with Pyrazolidinone Acrylimides. Ma, G.; Fujita, T.; Sibi, M. P. Tetrahedron Lett. 2015, 56, 3571-3574. DOI:10.1016/j.tetlet.2015.02.00
  10. Programmed degradation of oligomeric/polymeric materials derived from renewable bio-resources. Rajendran, S.; Raghunathan, R.; Krishnan, R.; Hevus, I.; Ugrinov, A.; Sibi, M. P.; Webster, D. C.; Jayaraman, S. Angew. Chem. Int. Ed., 2015, 54, 1159-1163. DOI: 10.1002/anie.201408492. Inside Cover. (Made news worldwide, Featured in Science)

2014

  1. Evaluation of Achiral Templates with Fluxional Brønsted Basic Substituents in Enantioselective Conjugate Additions. Adachi, S.; Takeda, N.; Sibi, M. P. Lett. 2014, 16, 6440–6443.
  2. Thiyl Radicals: From Simple Addition to Asymmetric Catalysis. Subramanian, H.; Moorthy, R.; Sibi, M. P. Chem. Int. Ed. 2014, 53, 13660-13662. DOI: 10.1002/anie.201408781
  3. Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts. Ma, G.; Sibi, M. P. Chem. Front. 2014, 1, 1152-1156. DOI: 10.1039/C4QO00210E. Cover Article
  4. Evaluating thiourea architecture for intramolecular [2+2]-photocycloaddition of 4-alkenylcoumarins. Vallavoju, N.; Sermaurai, S.; Jocksuch, S.; Prabhakaran, M. T.; Sibi, M. P.; Jayaraman, S. Synth. Catal. 2014, 356, 2763-2768. DOI: 10.1002/adsc.201400677
  5. Novel DMAP Catalysts with fluxional Chirality: Kinetic resolution of sec-alcohols and axially chiral biaryls. Ma, G.; Deng, J.; Sibi, M. P. Angew. Chem. Int. Ed. 2014, 53, 11818-11821. DOI: 10.1002/anie.201406684R1 Cover Article
  6. Enantioselective organo-photocatalysis mediated by atropisomeric thiourea derivatives. Vallavoju, N.; Sermadurai, S.; Jocksuch, S.; Sibi, M. P.; Jayaraman, S. Angew. Chem. Int. Ed, 2014, 53, 5604-5608. DOI: 10.1002/anie.201310940.
  7. Thermoset Coatings from Epoxidized Sucrose Soyate and Blocked, Biobased Dicarboxylic Acids. Kovash, C. S.; Pavlacky, E.; Selvakumar, S.; Sibi, M. P.; Webster, D. C. Chem. Suss. Chem. 2014, 7, 2289-2294.
  8. Regio- And Enantioselective Nitrone Cycloaddition To Alkynones For The Synthesis Of D4-Isoxazolines. Sibi, M. P.; Dunkle, K.; Rane, D. Heterocycles, 2014, 88, 1639-1647. DOI: 10.3987/COM-13-S(S)118
  9. Bio-Based Poly(vinyl ether)s and Their Application as Alkyd-Type Surface Coatings. Kalita, H.; Selvakumar, S.; Jayasooriyamu, A.; Fernando, S.; Samanta, S.; Bahr, J.; Alam, S.; Sibi, M.; Vold, J.; Ulven, C.; Chisholm, B. J. Green Chemistry, 2014, 16, 1974-1986. DOI: 10.1039/C3GC41868E

2013

  1. Csp3-F Bond Formation: A Free-Radical Approach. Sibi, M. P.; Landais, Y. Angew. Chem. Int. Ed. 2013, 52, 3570-3572.
  2. Polyamides Based on the Renewable Monomer, 1,13-Tridecane Diamine I:  Synthesis and Characterization of Nylon 13,T. He, J.; Samanta, S.; Selvakumar, S.; Lattimer, J.; Ulven. C.; Sibi, M. P.; Chisholm, B. Green Materials, 2013, 1, 114-124.
  3. Polyamides Based on the Renewable Monomer, 1,13-Tridecane Diamine I:  Synthesis and Characterization of Nylon 13,6. Samanta, S.; He, J.; Selvakumar, S.; Lattimer, J.; Ulven. C.; Sibi, M. P.; Chisholm, B. Polymer 2013, 54, 1141-1149.

2011

  1. Recent advances in nitrile oxide cycloaddition in the synthesis of 2-oxazolines. Rane, D.; Sibi, M. P. Curr. Org. Synth. 2011, 8, 616-627.

2010

  1. Addition of Free Radicals to Carbon-Carbon Multiple Bonds. Hata, S.; Sibi, M. P. Science of Synthesis, Stereoselective Synthesis I, pp 873-922, Thieme, 2010
  2. 3-Isoxazolidinone: A New Achiral Template for Enantioselective Transformations. Sibi, M. P.; Gustafson, B. A.; Coulomb, J. Bull. Kor. Chem. Soc. 2010, 31, 541-542.
  3. Enantioselective Diels-Alder Cycloadditions with b-Substituted Pyrazolidinone Propiolimides. Sibi, M. P.; Cruz, Jr. W.; Stanley, L. M. Synlett 2010, 889-892.

2009

  1. Recent Developments in the Construction of Quaternary Stereocenters via Cycloadditions. Rane, D.; Sibi, M. P. Chemistry Today, 2009, 27(6), 14-16.
  2. Nitrile Ylides: Diastereoselective Cycloadditions using Chiral Oxzolidinones Without Lewis Acid. Sibi, M. P.; Soeta, T.; Jasperse, C. P. Lett. 2009, 11, 5366–5369.
  3. A Diels-Alder Cycloaddition Strategy for the Kinetic Resolution of Chiral Pyrazolidinones. Sibi. M. P.; Kawashima, K.; Stanley, L. M. Lett. 2009, 11, 3894-3897.

2008

  1. Enantioselective Enolate Protonations: Friedel-Crafts Reactions with a-Substituted Acrylates. Sibi, M. P.; Coulomb, J.; Stanley, L. M. Chem. Int. Ed. 2008, 46, 9913-9915.
  2. Tin-Free Enantioselective Radical Reactions Using Silanes. Sibi, M. P.; Yang, Y.; Lee, S. Lett. 2008, 10, 5349-5352.
  3. exo- and Enantioselective Diels-Alder Reactions: Pyrazolidinone Auxiliaries as a Means to Enhanced exo Selectivity. Sibi, M. P.; Nie, X.; Shackleford, J. P.; Stanley, L. M.; Bouret, F. Synlett 2008, 2655-2658.
  4. Binding of Matrix Metalloproteinase Inhibitors to Extracellular Matrix: 3D-QSAR Analysis. Zhang, Y.; Lukacova, V.; Bartus, V.; Nie, A.; Sun, G.; Manivannan, E.; Ghorpade, S. R.; Jin, X.; Manyem, S.; Sibi, M. P.; Cook, G. R.; Balaz, S. 
Chemical Biology & Drug Design 2008, 72, 237-248.
  5. Copper (II)-Catalyzed Exo and Enantioselective Cycloadditions of Azomethine Imines. Sibi, M. ; Rane, D.; Stanley, L. M. Soeta, T. Org. Lett. 2008, 10, 2971-2974.
  6. Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions. Stanley, L. M.; Sibi, M. P. Rev. 2008, 108, 2887-2902.
  7. Chiral Lewis-Acid-Catalyzed Enantioselective Conjugate Radical Additions to a,b-Unsaturated 2-Pyridyl Ketones. Sibi, M. P.; Yang, Y-H. Synlett 2008, 83-88.

2007

  1. Enantioselective Radical Reactions. Stereoselective Aldol Synthesis from Cyclic Ketones. Sibi, M. P.; Nad, S. Chem. Int. Ed. 2007, 46, 9231-9234.
  2. Diastereoselective Conjugate Radical Additions to b-Pyranones. Sibi, M. P.; Yu, A. Synlett 2007, 3193-3197.
  3. Organocatalysis in Conjugate Amine Additions. Synthesis of β-Amino Acid Derivatives. Sibi, M. P.; Itoh, K. Am. Chem. Soc. 2007, 127, 8064-8065.
  4. Enantioselective 1,3-Dipolar Cycloadditions of Diazoacetates with Electron-Deficient Olefins. Sibi, M. P.; Stanley, L. M.; Soeta, T. Lett. 2007, 9, 1553-1556.
  5. Organocatalysis in Radical Chemistry. Enantioselective a-Oxyamination of Aldehydes. Sibi, M. P.; Hasegawa, M. Am. Chem. Soc. 2007, 129, 4124-4125.
  6. Enantioselective Conjugate Addition of Hydrazines to a,b-Unsaturated Imides. Synthesis of Chiral Pyrazolidinones. Sibi, M. P.; Soeta, T. Am. Chem. Soc. 2007, 129, 4522-4523.
  7. Enantioselective Diels-Alder Reactions. Effect of the Achiral Template on Reactivity and Selectivity. Sibi, M. P.; Chen, J.; Stanley, L. M. Synlett 2007, 298-302.
  8. The Role of Achiral Pyrazolidinone Templates in Enantioselective Diels-Alder Reactions: Scope, Limitations, and Conformational Insights. Sibi, M. P.; Stanley, L. M.; Nie, X.; Venkatraman, L.; Liu, M.; Jasperse, C. P. Am. Chem. Soc. 2007, 129, 395-405.
  9. Solution-Phase Parallel Synthesis of a Library of D2-Pyrazolines. Manyem, S.; Sibi, M.P.; Lushington, G. H.; Neuenswander, B.; Schoenen, F.; Aubé, J. Comb. Chem. 2007, 9, 20-28.

2006

  1. Enantioselective 1,3-Dipolar Cycloaddition of Nitrile Imines to a-Substituted and a,b-Disubstituted a,b-Unsaturated Carbonyl Substrates: A Method for Synthesizing Dihydropyrazoles Bearing a Chiral Quaternary Center. Sibi, M. P.; Stanley, L. M.; Soeta, T. Synth. Catal. 2006, 2371-2375.
  2. Fluxional Additives: A Second Generation Control in Enantioselective Catalysis. Sibi, M. P.; Manyem, S.; Palencia, H. Am. Chem. Soc. 2006, 128, 13660-13661.
  3. Pyrones to Pyrans: Enantioselective Radical Additions to Acyloxy Pyrones. Sibi, M. P.; Zimmerman, J. Am. Chem. Soc. 2006, 128, 13346-13347.
  4. Enantioselective Conjugate Radical Addition to a’-Hydroxy Enones. Lee, S.; Lim, C. J.; Kim, S.; Subramaniam, R.; Zimmerman, J.; Sibi, M. P. Lett. 2006, 8, 4311-4313.
  5. Enantioselective Radical Reactions. Formation of Chiral Quaternary Centers. Sibi, M. P.; He, L. Synlett 2006, 689-692.
  6. Enantioselective Radical Reactions. Evaluation of Nitrogen Protecting Groups in the Synthesis of β2-Amino Acids. Sibi, M. P.; Patil, K. Tetrahedron: Asymmetry 2006, 17, 516-519.

2005

  1. Stereoselective Conjugate Radical Additions: Application of a Fluorous Oxazolidinone Chiral Auxiliary for Efficient Tin Removal. Hein, J. E.; Zimmerman, J.; Sibi, M. P.; Hultin, P. G. Lett. 2005, 7, 2755-2758.
  2. Enantioselective Cycloadditions with a,b-disubstituted Acrylimides. Sibi, M. P.; Ma, Z.; Itoh, K.; Prabagaran, N.; Jasperse, C. P. Lett. 2005, 7, 2349-2352.
  3. Enantioselective Rhodium Enolate Protonations. A New Methodology for the Synthesis of b2-Amino Acids. Sibi, M. P.; Tatamidani, H.; Patil. K. Lett. 2005, 7, 2571-2573.
  4. Enantioselective Radical Methods for Lactone Synthesis. Use of Unprotected Haloalcohols as Radical Precursors. Sibi, M. P.; Guerrero, M. A. Synthesis 2005, 1528-1532.
  5. An Entry to Chiral Dihydropyrazole Scaffolds: Enantioselective [3 + 2] Cycloaddition of Nitrile Imines. Sibi, M. P.; Stanley, L. M.; Jasperse, C. P. Am. Chem. Soc. 2005, 127, 8276-8277.
  6. Enantioselective H-Atom Transfer Reactions. Synthesis of Formaldehyde Aldol Products. Sibi, M. P.; Patil, K. Lett. 2005, 6, 1453-1456.
  7. Novel Indole Chemistry in the Synthesis of Heterocycles. Gribble, G. W.; Saulnier, M. G.; Pelkey, E. T.; Kishbaugh, T. L. S.; Liu, Y.; Jiang, J.; Trujillo, H. A.; Keavy, D. J.; Davis, D. A.; Conway, S. C.; Switzer, F. L.; Roy, S.; Silva, R. A.; Obaza-Nutaitis, J. A.; Sibi, M. P.; Moskalev, N. V.; Barden, T. C.; Chang, L.; Simon, W.; Pelcman, B.; Sponholtz, III, W. R.; Chau, R. W.; Alison, B.; Garass, S. D.; Sinha, M. S.; McGowan, M. A.; Reese, M. R.; Harpp, K. S. Org. Chem. 2005, 9, 1493-1519.
  8. Enantioselective Addition of Nitrones to Activated Cyclopropanes. Sibi, M. P.; Ma, Z. Jasperse, C. P. Am. Chem. Soc. 2005, 127, 5764-5765.
  9. Enantioselective Radical Addition/trapping Reactions with ab-Disubstituted Enoates. Synthesis of anti-Propionate Aldols. Sibi, M. P.; Petrovic, G.; Zimmerman, J. Am. Chem. Soc. 2005, 127, 2390-2391.

2004

  1. Enantioselective Diethylzinc Additions to Aldehydes Catalyzed by Chiral Relay Ligands. Sibi, M. P.; Stanley, L. A. Tetrahedron: Asymmetry 2004, 16, 3353-3356.
  2. The nature, limits, and implications of asymmetric autocatalysis. Manyem, S.; Sibi, M. P. Chemtracts 2004, 17, 255-260.
  3. Chiral Relay in Enantioselective Conjugate Radical Additions Using Pyrazolidinone Templates. How Does Metal Geometry Impact Selectivity? Sibi, M. P.; Prabagaran, N. Synlett 2004, 2421-2424.
  4. Enantioselective Diels-Alder reactions of 3-(acyloxy)acrylates. Sibi, M. P.; Matsunaga, H. Tetrahedron Lett. 2004, 45, 5925-5929.
  5. Application of Enantioselective Radical Reactions: Synthesis of (+)-Ricciocarpin A and B. Sibi, M. P.; He, L. Lett. 2004, 6, 1749-1752.
  6. Enantioselective Total Synthesis of (-)-Stemoamide. Sibi, M. P.; Subramanain, T. Synlett 2004, 1211-1214.
  7. Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions. Sibi, M. P.; Itoh, K.; Jasperse, C. P. Am. Chem. Soc. 2004, 126, 5366-5367.
  8. Enantioselective H-atom Transfer Reactions. Synthesis of b2-Amino Acids. Sibi, M. P.; Patil, K. Chem. Int. Ed. 2004, 43, 1235-1238.
  9. Exo Selective Enantioselective Nitrone Cycloadditions. Sibi, M. P.; Ma, Z.; Jasperse, C. P. Am. Chem. Soc. 2004, 126, 718-719.
  10. Synthesis of Oxacycles by Tandem Radical Addition-Cyclization Reactions. Sibi, M. P.; Patil, K.; Rheault, T. R. J. Org. Chem. 2004, 372-384.

2003

  1. Tin-Free Radical-Mediated C–C-Bond Formations. Manyem, S.; Zimmerman, J.; Patil, K.; Sibi, M. P. Chemtracts 2003, 16, 819-826.
  2. Enantioselective Radical Allylation Reactions using Chiral Lanthanide Lewis Acids. Sibi, M. P.; Manyem, S.; Subramaniam, R. Tetrahedron, 2003, 59, 10575-10580.
  3. Enantioselective Radical Reactions. The Use of Metal Triflimides as Lewis Acids. Sibi, M. P.; Petrovic, G. Tetrahedron: Asymmetry, 2003, 15, 2879-2882.
  4. Tandem radical reactions and ring-closing metathesis. Application in the synthesis of cyclooctenes. Sibi, M. P.; Aasmul, M.; Hasegawa, H.; Subramanian, T. Lett. 2003, 5, 2883-2886.
  5. Enantioselective Synthesis of ab-Disubstituted-b-Amino Acids. Sibi, M. P.; Prabagaran, N.; Ghorpade, S. G.; Jasperse, C. P. Am. Chem. Soc. 2003, 125, 11796-11797.
  6. A New Class of Modular Chiral Ligands with Fluxional Groups. Sibi, M. P.; Zhang, R.; Manyem. S. Am. Chem. Soc. 2003, 125, 9306-9307.
  7. Enantioselective Radical Conjugate Addition. A New Methodology for the Synthesis of Acetate Aldols. Sibi, M. P.; Zimmerman, J.; Rheault, T. R. Chem. Int. Ed. 2003, 42, 4521-4523.
  8. Enantioselective Radical Reactions. Sibi, M. P.; Manyem. S.; Zimmerman, J. Rev. 2003, 103, 3263-3296.
  9. Radical-Mediated Annulation Reactions. Rheault, T. R.; Sibi, M. P. Synthesis 2003, 803-819.
  10. Chiral Relay: A Novel Strategy for the Control and Amplification of Enantioselectivity in Chiral Lewis Acid Promoted Reactions. Corminboeuf, O.; Quaranta, L.; Renaud, ; Liu, M.; Jasperse, C. P.; Sibi, M. P. Chem. Eur. J. 2003, 9, 28-35.
  11. Determination of Corrosion on Aluminum Alloy under Protective Coatings Using Fluorescent Probes. Sibi, M. P.; Zong, Z. Progress in Organic Coatings 2003, 47, 8-15.

2002

  1. Crotylations of a-Carbonyl Radicals with Crotylstannane. Sibi, M. P.; Miyabe, H. Lett. 2002, 4, 3435-3438.
  2. An Efficient Method for the Synthesis of Succinate Based MMP Inhibitors. Sibi, M. P.; Hasegawa, Org. Lett. 2002, 4, 3347-3349.
  3. A Convenient Method for the Conversion of N-Acyl Oxazolidinones to Hydroxamic Acids. Sibi, M. P.; Hasegawa, H.; Ghorpade, S. R. Lett. 2002, 4, 3343-3346.
  4. Lanthanide Lewis Acid-mediated Enantioselective Conjugate Radical Additions. Sibi, M. P.; Manyem, S. Lett. 2002, 4, 2929-2932.
  5. Recent Advances in the Stereoselective Synthesis of b-Amino Acids. Liu, M.; Sibi, M. P. Tetrahedron 2002, 58, 7991-8035.
  6. Temperature Dependent Reversal of Stereochemistry in Enantioselective Conjugate Amine Additions. Sibi, M. P.; Gorikunti, U.; Liu, M. Tetrahedron 2002, 58, 8357-8363.
  7. Enantioselective Conjugate Addition of Silylketene Acetals to Enamidomalonates. Synthesis of b-Amino Acid Derivatives. Sibi, M. P.; Chen, J. Lett. 2002, 4, 2933-2936.
  8. Free Radical Mediated Conjugate Additions. Enantioselective Synthesis of (-)-Enterolactone, (-)-Arctigenin, (-)-Isoarctigenin, (-)-Nephrosetranic Acid and (-)-Roccellaric Acid. Sibi, M. P.; Liu, P.; Ji, J.; Hajra, S.; Chen, J. Org. Chem. 2002, 67, 1738-1745. Cover Article
  9. Acyclic Diastereoselection in Prochiral Radical Addition to Prochiral Olefins. Sibi, M. P.; Rheault, T. R.; Chandramouli, S. V.; Jasperse, C. P. Am. Chem. Soc. 2002, 124, 2924-2930.
  10. The Role of the Achiral Template in Enantioselective Transformations. Radical Conjugate Additions to a-Methylacrylates Followed by Hydrogen Atom Transfer. Sibi, M. P.; Sausker, J. B. Am. Chem. Soc. 2002, 124, 984-991.

2001

  1. Enantioselective Conjugate Addition of Organo-magnesium Amides to Enamidomalonates. Synthesis of Either Enantiomer of b-Amino Acid Derivatives. Sibi, M. P.; Asano, Y. Am. Chem. Soc. 2001, 123, 9708-9709.
  2. Enantioselective Tandem Radical Reactions. Vicinal Difunctionalization in Acyclic Systems with Control over Relative and Absolute Stereochemistry. Sibi, M. P.; Chen, J. Am. Chem. Soc. 2001, 123, 9472-9473.
  3. A New Approach to Enantiocontrol and Enantioselectivity Amplification. Chiral Relay in Diels-Alder Reactions. Sibi, M. P.; Venkatraman, L.; Liu, M.; Jasperse, C. P. Am. Chem. Soc. 2001, 123, 8444-8445.
  4. Enantioselective H-Atom Transfer Reactions. Synthesis of a-Amino Acids. Sibi, M. P.; Asano, Y.; Sausker, J. Chem. Int. Ed. 2001, 40, 1293-1296.
  5. Enantioselective Conjugate Addition of Hydroxylamines to Pyrazolidinone Acrylamides. Sibi, M. P.; Liu, M. Lett. 2001, 3, 4181-4184.
  6. Radical-Mediated Annulation Reactions. A Versatile Strategy for the Preparation of a Series of Carbocycles. Sibi, M. P.; Chen, J.; Rheault, T. R. Lett. 2001, 3, 3679-3681.
  7. Highly Diastereoselective Radical Addition-Cyclization Strategy: Facile Synthesis of Substituted Furans. Sibi, M. P.; Rheault, T. R.; Miyabe, H.; Patil, K.; Jasperse, C. P. R. Acad. Sci. Ser II C 2001, 4, 581-584.
  8. Reversal of Stereochemistry in Enantioselective Transformations. Can they be Planned or are they just Accidental. Sibi, M. P.; Liu, M. Org. Chem. 2001, 5, 719-755.
  9. Enantioselective Synthesis of Peperomins A-D and Analog. Examination of Diastereoselective Cuprate Conjugate Additions to Enoyl Oxazolidinones. Sibi, M. P.; Johnson, M. D.; Punniyamurthy, T. J. Chem. 2001, 79, 1546-1555.

2000

  1. Chiral Lewis Acid Catalyzed Conjugate Addition of N-benzylhydroxylamine to b-Aryl Enoates. Enantioselective Synthesis of b-Amino Acid Precursors. Sibi, M. P.; Liu, M. Lett. 2000, 2, 3393-3396.
  2. Enantioselective Conjugate Additions. Sibi, M. P.; Manyem, S. Tetrahedron 2000, 56, 8033-8061.
  3. Higher Selectivity at Higher Temperatures! Effect of Precursor Stereochemistry on Diastereoselectivity in Radical Allylations.  Insight into the Role of the Lewis Acid.  Sibi, M. P.; Rheault, T. R. Am. Chem. Soc. 2000, 122, 8873-8879.
  4. Enantioselective Synthesis of cisN-Carbobenzyloxy-3-Hydroxyproline Ethylester. Sibi, M. P.; Christensen, J. W. in Catalysts for the Fine Chemical Industry Roberts, S. M., Ed., Wiley, Oxford, 2000.
  5. A Short Synthesis of Both Enantiomers of Enterolactone. Sibi, M. P.; Liu, P.; Johnson, M. D. J. Chem. 2000, 78, 133-139.
  6. A New Methodology for the Synthesis of b-Amino Acids. Sibi, M. P.; Deshpande, P. K. Chem. Soc. Perkin Trans1 2000, 1461-1466.

1999

  1. Stereoselective Conjugate Additions to Enoates. Sibi, M. P.; Liu, M. Enantiomer 1999, 4, 575-590.
  2. Are Two Phenyl Groups Better than One? Synthesis and Applications of (R)-4-Diphenylmethyl-2-oxazolidinone. Sibi, M. P. Aldrichimica Acta 1999, 32, 93-101.
  3. Enantiospecific Synthesis of (-)-Slaframine and Related Hydroxylated Indolizidines. Utilization of a Nucleophilic Alaninol Synthon Derived from Serine. Sibi, M. P.; Christensen, J. W. Org. Chem. 1999, 64, 6434-6442.
  4. Free Radical-Mediated Intermolecular Conjugate Additions. Effect of the Lewis Acid, Chiral Auxiliary, and Additives on Diastereoselectivity.  Sibi, M., P.; Ji, J.; Sausker, J. B.; Jasperse, C. P. Am. Chem. Soc. 1999, 121, 7517-7526.
  5. Investigations of a Nucleophilic Alaninol Synthon Derived from Serine. Sibi, M. P.; Rutherford, D.; Renhowe, P. A.; Li, B. Am. Chem. Soc. 1999, 121, 7509-7516.
  6. Reversal of Stereochemistry in Diethylzinc Addition to Aldehydes by a Simple Change of the Backbone Substituent in L-Serine Derived Ligands. Sibi, M. P.; Chen, J-x.; Cook, G. R. Tetrahedron Lett. 1999, 40, 3301-3304.
  7. Enantioselective Reduction of Ketones. Examination of Bifunctional Ligands. Sibi, M. P.; Cook, G. R.; Liu, P. Tetrahedron Lett. 1999, 40, 2477-2480.
  8. Enantioselective Radical Reactions. Sibi, M. P.; Porter, N. A. Chem. Res. 1999, 32, 163-171.

1998

  1. Chiral Lewis Acid Catalysis in Conjugate Additions of O-Benzylhydroxylamine to Unsaturated Amides. Enantioselective Synthesis of b-Amino Acid Precursors. Sibi, M. P.; Shay, J. J.; Liu, M.; Jasperse, C. P. Am. Chem. Soc. 1998, 120, 6615-6516.
  2. Synthesis of Silicon Containing Alanines. Sibi, M. P.; Harris, B. J.; Shay, J. S.; Hajra, S. Tetrahedron, 1998, 54, 7221-7228.

1997

  1. Intermolecular Free Radical Reactions on Solid Support. Allylation of Esters. Sibi, M. P.; Chandramouli, S. V. Tetrahedron Lett. 1997, 38, 8929.
  2. Enantioselective Intermolecular Free Radical Conjugate Additions. Application of a Pyrazole Template. Sibi, M. P.; Shay, J. J.; Ji, J. Tetrahedron Lett. 1997, 38, 5955.
  3. A New Route to 3-Amino Sugars. A Concise Synthesis of L-Daunosamine and D-Ristosamine Derivatives.  Sibi, M. P.; Lu, J.; Edwards, J. Org. Chem. 1997, 62, 5864.
  4. Practical and Efficient Enantioselective Conjugate Radical Additions. Sibi, M. P.; Ji, J. Org. Chem. 1997, 62, 3800.
  5. Regio-and Stereocontrolled Conjugate Radical Addition to a Desymmetrized Fumarate. An Efficient Synthesis of (-)-Nephrosteranic Acid and (-)-Roccellaric Acid. Sibi, M. P.; Ji, J. Chem. Int. Ed. Engl. 1997, 36, 274.

1996

  1. Chiral Lewis Acid Catalysis in Radical Reactions: Enantioselective Conjugate Radical Additions.  Sibi, M. P.; Ji, J.; Wu, J. H.; Gurtler, S.; Porter, N. A. Am. Chem. Soc. 1996, 118, 9200-9201.
  2. Enantiospecific Synthesis of Trisubstituted Butyrolactone Natural Products and their Analogs. Sibi, M. P.; Lu, J.; Talbacka, C. L. Org. Chem. 1996, 61, 7848.
  3. Acyclic Stereocontrol in Radical Reactions. Diastereoselective Radical Addition/Allylation of N-Propenoyloxazolidinone. Sibi, M. P.; Ji, J. Org. Chem., 1996, 61, 6090.
  4. Radical Methods in the Synthesis of Heterocyclic Compounds. Sibi, M. P.; Ji, J. Progress in Heterocyclic Chemistry, 1996, 8, 14.
  5. Synthesis and Structural Characterization of Chiral Amine Alcohol Complexes of Aluminum. Atwood, D. A.; Gabbai, F. P.; Lu, J.; Remington, M. P.; Rutherford, D.; Sibi, M. P. Organometallics 1996, 15, 2308.
  6. Participation of Organotin Lewis Acids in Radical Reactions: Manipulation of Rotamer Population in N-Enoyloxazolidinones. Sibi, M. P.; Ji, J. Am. Chem. Soc. 1996, 118, 3063.
  7. Regio- and Stereoselective Functionalization of Linear Dicarboxylic Acid Derivatives. A Sequential Aldol-Lactonization Strategy for the Synthesis of (-)-Roccellaric Acid, (-)-Protolichesterinic Acid, and (-)-Methylenolactocin. Sibi, P.; Deshpande, P. K.; La Loggia, A. J. Synlett 1996, 343.
  8. Acyclic Stereocontrol in Radical Reactions. r-selectivity using Oxazolidinone Auxiliaries.  Sibi, M. P.; Ji, J. Chem., Int. Ed. Engl. 1996, 35, 190.

1995

  1. Preparation of Alkyne Derivatives via Organolithium Intermediates. Sibi, M. P. Lithium Link, Newsletter, 1995.
  2. A New Chiral Oxazolidinone Derived from Diphenyl Alaninol. Aldol, Alkylation, and Diels-Alder Reactions. Sibi, M. P.; Deshpande, P. K.; Ji, J. Tetrahedron Lett. 1995, 36, 8965.
  3. Synthesis of N-BOC-D-Diphenylalanine from L-Serine Methylester Hydrochloride. Sibi, M. P.; Deshpande, P. K.; LaLoggia, A. J.; Christensen, J. W. Tetrahedron Lett. 1995, 36, 8961.
  4. Lewis Acid Mediated Intermolecular b-Selective Radical Additions to N-Enoyloxazolidinones. Sibi, M. P.; Jasperse, C. P.; Ji, J. Am. Chem. Soc. 1995, 117, 10779.
  5. Intramolecular Hydrosilylations of b-Unsaturated Acyloxy Silanes. A Convenient Synthesis of (2S,3R)-N-BOC-3-Hydroxyproline Methyl Ester.  Sibi, M. P.; Christensen, J. W. Tetrahedron Lett. 1995, 36, 6213.
  6. Chemoselective Dieckmann-Like Condensations Using N-Methoxy-N-Methylamides. Sibi, M. P.; Christensen, J. W.; Kim, S.-G.; Eggen, M.; Stessman, C.; Oien, L. Tetrahedron Lett. 1995, 36, 6209.
  7. a-Ketoamides and 1,2-Diketones from N,N’-Dimethoxy-N,N’-Dimethyl Ethanediamide. A Synthetic and Mechanistic Investigation. Sibi, M. P.; Marvin, M.; Sharma, R. Org. Chem. 1995, 60, 5016.
  8. A Convenient Synthesis of N-Methoxy-N-Methylamides from Carboxylic Acids. Sibi, M. P.; Stessman, C. S.; Schultz, J. A.; Christensen, J. W.; Lu, J.; Marvin, M. Commun. 1995, 28, 1255.

1994

  1. A Convenient Synthesis of Both Enantiomers of trans-2,5-Bishydroxymethylpyrrolidine. Lipase Mediated Resolutions. Sibi, M. P.; Lu, J. Tetrahedron Letters 1994, 35, 4915.
  2. A New Electrophilic Alaninol Synthon. Synthesis of Protected D-Amino Alcohols From L-Serine.  Sibi, M. P.; Rutherford, D.; Sharma, R., Chem. Soc. Perkin Trans 1, 1994, 1675.
  3. Synthesis of Tetrahydrofuran Lignans. A Review. Gaboury, J. A.; Sibi, M. P. Journal of the Indian Institute of Science 1994, 74, 135.

1993

  1. Enantiocontrolled Synthesis of Burseran, Brassilignan, Dehydroxycubebin, and Other Unnatural Tetrahydrofuran Lignans in Both Enantiomeric Forms. Application of Intermolecular Nitrile Oxide Cycloadditions and Lipase Mediated Resolutions.  Gaboury, J. A.; Sibi, M. P. Org Chem. 1993, 58, 2173.
  2. Chemistry of N-Methoxy-N-Methylamides. Applications in Synthesis. Sibi, M. P. Prep. Proced. Int. 1993, 25, 15.

1992

  1. Syntheses and Diels-Alder Cycloaddition Reactions of 4H-Furo[3,4-b]indoles. A Regiospecific Diels-Alder Synthesis of Ellipticine. Gribble, G. W.; Keavey, D. J.; Davis, D. A.; Saulnier, M. G.; Pelcman, B.; Barden, T. C.; Sibi, M. P.; Olson, E. R.; BelBruno, J. J. Org. Chem. 1992, 57, 5878.
  2. Application of Enzymatic Methods for the Chiral Synthesis of 5-Substituted-2-Furanones. Sibi, M. P.; Gaboury, J. A. Tetrahedron Lett. 1992, 33, 5681.
  3. A Novel Thermolytic Annulation of an Oxazolidinione: An Enantiospecific Synthesis of (-)-Slaframine. Sibi, M. P.; Christensen, J. W.; Li, B.; Renhowe, P. A. Org. Chem. 1992, 57, 4329.
  4. Regio- and Stereocontrolled Hydroborations of Chiral Allyl Amines. Synthesis of Amino Alcohols. Sibi, M. P.; Li, B. Tetrahedron Lett. 1992, 33, 4115.
  5. Reductions of a-Oxo-N-Methoxy-N-Methylamides. A Convenient Synthesis of 1,2-Diols. Sibi, M. P.; Sharma, R. Synlett 1992, 497.
  6. N,N’-Dimethoxy-N,N’-Dimethylethanediamide: A Useful a-Oxo-N,O-Dimethyl Amide and 1,2-Dicarbonyl Synthon. Sibi, M. P.; Sharma, R.; Paulson, K. L. Tetrahedron Lett. 1992, 33, 1941.
  7. Synthesis of Lignan Natural Products (±)Dehydroxycubebin and (±)Burseran by Intermolecular Nitrile Oxide Cycloaddition. Sibi, M. P; Gaboury, J. A. Synlett 1992, 83.
  8. A Convenient Synthesis of 3-Alkyltetronic Acids from 3-Acyltetronic Acids. Sibi, M. P.; Sorum, M. T.; Bender, J. A.; Gaboury, J. A. Commun. 1992, 22, 809.

1991

  1. Nitrogen-15 NMR Spectroscopy: Nitrogen-15 Chemical Shifts of Alkyl Thioureas. Sibi, M. P. Reson. Chem. 1991, 29, 401.
  2. Nitrogen-15 NMR Spectroscopy: Nitrogen-15 Chemical Shifts of 1,2-Diaminobenzenes and 1,8-Diaminonaphthalenes. Sibi, M. P. Reson. Chem. 1991, 29, 400.

1990

  1. A New Nucleophilic Alaninol Synthon Derived From Serine. Sibi, M. P.; Renhowe, P. A. Tetrahedron Lett. 1990, 31, 7407.
  2. Amino Acids as Precursors to Indolizidine Alkaloids. Sibi, M. P.; Christensen, J. W. Tetrahedron Lett. 1990, 31, 5689.

1988

  1. Palladium Mediated Biomimetic Synthesis of Narwedine. Holton R. A.; Sibi, M. P.; Murphy, W. J. Am. Chem. Soc. 1988, 110, 314.

1987

  1. Overriding Normal Friedel-Crafts Regioselectivity in Cycliacylation. Regiospecific Carbodesilylation and Parham Cyclization Routes to 7-Methoxy-1-indanols. Sibi, M. P.; Shankaran, K.; Alo, B. J.; Hahn, W. R.; Snieckus, V. Tetrahedron Lett. 1987, 28, 2933.

1986

  1. Anionic Aromatic Ring Annelation of o-Allyl Benzamides. Regiospecific Synthesis of Naphthols and Naphthoquinones. Sibi, M. P.; Dankwardt, J. W.; Snieckus, V. Org. Chem. 1986, 51, 271.

1985

  1. Combinational O-Aryl Carbamate and Benzamide Directed Ortho Metalation Reactions. Synthesis of Ochratoxin A and Ochratoxin B. Sibi, M. P.; Chattopadhyay, S.; Dankwardt, J. W.; Snieckus, V. Am. Chem. Soc. 1985, 107, 6512.
  2. Dilithiated Synthons of Tertiary Benzamides, Phthalamides, and O,O’-Aryl Dicarbamates. Mills, R. J.; Horvath, R. F.; Sibi, M. P.; Snieckus, V. Tetrahedron Lett. 1985, 26, 1145.
  3. Synthesis and Deamination of 7-12-Dihydrobenz[a]anthracen-7,12-imines. A New Benz[a]anthracene Synthesis. Gribble, G. W.; LeHoullier, C. S.; Sibi, M. P.; Allen, R. W. Org. Chem. 1985, 50, 1611.

1984

  1. Synthesis and Diels-Alder Reactions of 1,3-Dimethyl-1,4-(phenylsulfonyl)-4H furo (3,4-b)indole.  A New Annulation Strategy for the Construction of Ellipticine and Isoellipticine.  Gribble, G. W.; Saulnier, M. G.; Sibi, M. P.; Obaza-Nutaitis, J. A. J. Org. Chem. 1984, 49, 4518.
  2. Benzamide Directed Ortho Metalation. A Route to the A/B Ring Synthon of Daunomycinone. Sibi, M. P.; Altintas, N.; Snieckus, V. Tetrahedron 1984, 40, 4593.
  3. Ortholithiated Tertiary Benzamides. Magnesium Transmetalation and Synthesis of Phthalides and Isocoumarins Including Mellein and Kigelin. Sibi, M. P.; Miah, M. A. J.; Snieckus, V. Org. Chem. 1984, 49, 737.

1983

  1. Directed Ortho Metalation of Silyloxybenzamides: Anion Induced O—> C Silicon Rearrangement. Billedeau, R. J.; Sibi, M. P.; Snieckus, V. Tetrahedron Lett. 1983, 24, 4515.
  2. Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. 15N Chemical Shifts of Para-Substituted Hindered Anilines and Related Compounds. Sibi, M. P.; Prince, E. C.; LeMelle, J.; Lichter, R. L. Spectroscopy: An International Journal 1983, 2, 198.
  3. The Directed Ortho Lithiation of O-Aryl Carbamates. An Anionic Equivalent of the Fries Rearrangement. Sibi, M. P.; Snieckus, V. Org. Chem. 1983, 48, 1935.
  4. Synthesis and Deamination of 1,4-dihydronaphthalen-1,4-imines: A Convenient Naphthalene Synthesis. Gribble, G. W.; Sibi, M. P.; Kumar, S.; Kelly, W. J. Synthesis 1983, 502.

1982

  1. Reactions of Sodium Borohydride in Acidic Media; IX. Deoxygenation of 1,4-Epoxy-1,4-dihydronaphthalenes; A Convenient Naphthalene Synthesis. Gribble, G. W.; Kelly, W. J.; Sibi, M. P. Synthesis 1982, 143.

1981

  1. Dichlorocarbene-Induced Deamination of Naphthalen-1,4-imines and Anthracen-9-10-imines. Gribble, G. W.; Allen, R. W.; LeHoullier, C. S.; Eaton, J. T.; Easton, Jr., R. S.; Slayton, R. I.; Sibi, M. P. Org. Chem. 1981, 46, 1025.

1980

  1. Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. 15N-19F Coupling Constants in Fluoropyridines and Fluoroanilines. Sibi, M. P.; Lichter, R. L. Magn. Resonance 1980, 14, 494.

1979

  1. Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. Natural Abundance Nitrogen-15 Chemical Shifts of Alkyl and Aryl Substituted Ureas. Sibi, M. P.; Lichter, R. L. Org. Chem. 1979, 44, 3017.

1977

  1. Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. Natural Abundance Nitrogen-15 Chemical Shifts of Ring-Methylated N,N-dimethylanilines. Effect of Inhibition of Conjugation. Sibi, M. P.; Lichter, R. L. Org. Chem. 1977, 42, 2999.