Propargyl Radicals in Organic Synthesis

Marcus Muresan, Dr. Hariharaputhiran Subramanian, Prof Mukund P. Sibi, Prof. James R. Green​

ACS Sustainable Chem. Eng.

Evaluation of 3-Allyl-5-vinylveratrole in Latex Copolymerization with an Acrylic Monomer from High Oleic Soybean Oil​​

Yehor Polunin, Timothy J. Burns, Eric M. Serum, Mukund P. Sibi, Andriy Voronov ​

Angew. Chem. Int. Ed.

The Size-Accelerated Kinetic Resolution of Secondary Alcohols

Benjamin Polloth, Mukund P. Sibi and Hendrik Zipse


ACS Sustainable Chem. Eng.

Novel Biobased Furanic Diols as Potential Alternatives to BPA: Synthesis and Endocrine Activity Screening​

Catherine A. Sutton, Alexander Polykarpov, Keimpe Jan van den Berg, Alexander Yahkind, Linda J. Lea, Dean C. Webster and Mukund P. Sibi


A preliminary environmental assessment of epoxidized sucrose soyate (ESS)-based biocomposite

Shokoofeh Ghasemi, Mukund P. Sibi, Chad A. Ulven, Dean C. Webster and Ghasideh Pourhashem


Structurally unique PARP-1 inhibitors for the treatment of prostate cancer

Ali Divan, Mukund P. Sibi and Alexei Tulin


Helvetica Chim. Acta.

Asymmetric Synthesis of 2,3-Disubstituted Cyclic Ketones by Enantioselective Conjugate Radical Additions

Sukanya Nad and Mukund P. Sibi

ACS Sustainable Chem. Eng.

Biobased, Nonisocyanate, 2K Polyurethane Coatings Produced from Polycarbamate and Dialdehyde Cross-linking

Samantha D. Silbert, Eric M. Serum, John LaScala, Mukund P. Sibi and Dean C. Webster

Sci. China Chem.

Special issue on organic free radical chemistry

Mukund P. Sibi, Chaozhong Li and Ning Jiao

Pure and Applied Chemistry

New AB type monomers from lignocellulosic biomass

Eric M. Serum, Catherine A. Sutton, Anna C. Renner, Dyuti Dawn and Mukund P. Sibi



Fine chemicals from a biomass-derived dicarboxylic acid: chiral bisoxazolines and their application in enantioselective Diels-Alder reactions

Sermadurai Selvakumar, Alisa Fairweather, Angel Ugrinov and Mukund P. Sibi


Overview of enterolactone biological properties and total synthesis

Quinlyn T. Waulters, Waidath Bio-Sawe, Russell Hofmann and Mukund P. Sibi

ACS Sustainable Chem. Eng.

Renewable Reactive Diluents as Practical Styrene Replacements in Biobased Vinyl Ester Thermosets

Arvin Z. Yu, Eric M. Serum, Anna C. Renner, Jonas M. Sahouani, Mukund P. Sibi and Dean C. Webster


Dibenzofuran-4,6-bis(oxazoline) (DBFOX). A novel trans-chelating bis(oxazoline) ligand for asymmetric reactions

Kennosuke Itoh and Mukund P. Sibi

Green Chem.

Catalyst-free lignin valorization by acetoacetylation. Structural elucidation by comparison with model compounds

Eric M. Krall, Eric M. Serum, Mukund P. Sibi and Dean C. Webster


Dynamic kinetic resolution of biaryl atropisomers by chiral dialkylaminopyridine catalysts

Gaoyuan Ma, Chao Deng, Jun Deng and Mukund P. Sibi

Green Chem.

Valorization of 2,5-furandicarboxylic acid. Diels-Alder reactions with benzyne

Eric M. Serum, Sermadurai Selvakumar, Nicolas Zimmermann and Mukund P. Sibi

ACS Sustainable Chem. Eng.

Polymers from Bioderived Resources: Synthesis of Poly(silylether)s from Furan Derivatives Catalyzed by a Salen-Mn(V) Complex

Srikanth Vijjamarri, Sarah Streed, Eric M. Serum, Mukund P. Sibi and Guodong Du

J. Chromatogr. A.

Size exclusion chromatography of lignin: The mechanistic aspects and elimination of undesired secondary interactions

Anastasia A. Andrianova, Natallia A. Yeudakimenka, Samuel L. Lilak, Evguenii I. Kozliak, Angel Ugrinov, Mukund P. Sibi and Alena Kubatova


Directed ortho-Metalation of Aryl Amides, O-Carbamates, and Methoxymethoxy Systems: Directed Metalation Group Competition and Cooperation

M. A. Jalil Miah, Mukund P. Sibi, S. Chattopadhyay, Oluwole B. Familoni and Victory Snieckus


Directed ortho-Metalation of O-Aryl N,N-Dialkylcarbamates: Methodology, Anionic ortho-Fries Rearrangement, and Lateral Metalation

M.A. Jalil Miah, Mukund P. Sibi, S. Chattopadhyay, Oluwole B. Familoni and Victor Snieckus


Chiral Lewis acids in Org. Synth.

Copper-based Chiral Lewis Acids

Karthikeyan Iyanar and Mukund P. Sibi


Enantioselective and Diastereoselective Conjugate Radical Additions to α-Arylidene Ketones and Lactones

Changjia Zhao and Mukund P. Sibi

AIP Adv.

Origin of stretched-exponential photoluminescence relaxation in size-separated silicon nanocrystals

Samuel L. Brown, Retheesh Krishnan, Ahmed Elbaradei, Jayaraman Sivaguru, Mukund P. Sibi and Erik K. Hobbie

J. Clean. Prod.

Life cycle assessment of photodegradable polymeric material derived from renewable bioresources

Claudia Isola, Heidi L. Sieverding, Ramya Raghunathan, Mukund P. Sibi, Dean C. Webster, Jayaraman Sivaguru and James J. Stone


J. Mater. Chem. C.

Synthesis of silicon quantum dots using cyclohexasilane (Si6H12)

Srinivasan Guruvenket, Justin M. Hoey, Kenneth J. Anderson, Matthew T. Frohlich, Retheesh Krishnan, Jayaraman Sivaguru, Mukund P. Sibi and Philip Boudjouk

Angew. Chem. Int. Ed.

Organophotocatalysis: Insights into the Mechanistic Aspects of Thiourea-Mediated Intermolecular [2+2] Photocycloadditions

Nandini Vallavoju, Dr. Sermadurai Selvakumar, Dr. Barry C. Pemberton, Dr. Steffen Jockusch, Prof. Dr. Mukund P. Sibi, Prof. Dr. Jayaraman Sivaguru

ACS Sustain. Chem. Eng.

Synthesis and Characterization of Polyurethane Networks Derived from Soybean-Oil-Based Cyclic Carbonates and Bioderivable Diamines

Satyabrata Samanta, Sermadurai Selvakumar, James Bahr, Dona Suranga Wickramaratne, Mukund Sibi and Bret J. Chisholm

J. Photoch. Photobio. A

Evaluating thiourea/urea catalyst for enantioselective 6π-photocyclization of acrylanilides

Ramya Raghunathan, Steffen Jockusch, Mukund P. Sibi and J. Sivaguru


Chem. Rev.

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

Elango Kumarasamy, Ramya Raghunathan, Mukund P. Sibi and J. Sivaguru

Green Chem.

Linear polyester synthesized from furfural-based monomer by photoreaction in sunlight

Zhihan Wang, Brent Kastern, Katelyn Randazzo, Angel Ugrinov, Jonathan Butz, David W. Seals, Mukund P. Sibi and Qianli R. Chu

Chem. Eur. J.

Catalytic Kinetic Resolution of Biaryl Compounds

Gaoyuan Ma, Prof. Dr. Mukund P. Sibi

Chem. Eur. J.

Structural and Solubility Parameter Correlations of Gelation Abilities for Dihydroxylated Derivatives of Long-Chain, Naturally Occurring Fatty Acids

Mohan Zhang, Dr. Sermadurai Selvakumar, Prof. Xinran Zhang, Prof. Mukund P. Sibi, Prof. Richard G. Weiss

Org. Lett.

Characterization of Brønsted Acid–Base 
Complexes by 19F DOSY

Hariharaputhiran Subramanian, Craig P. Jasperse and Mukund P. Sibi

Tetrahedron Lett.

Lewis acid mediated diastereoselective intermolecular radical addition/trapping with pyrazolidinone acrylimides

GaoyuanMa TakehiroFujita and Mukund P. Sibi

Angew. Chem. Int. Ed.

Programmed Photodegradation of Polymeric/Oligomeric Materials Derived from Renewable Bioresources

Dr. Saravanakumar Rajendran, Ramya Raghynathan, Dr. Ivan Hevus, Retheesh Krishnan, Dr. Angel Ugrinov, Prof. Dr. Mukund P. Sibi, Prof. Dr. Dean C. Webster, Prof. Dr. Jayaraman Sivaguru


Org. Lett.

Evaluation of achiral templates with fluxional Brønsted basic substituents in enantioselective conjugate additions

Shinya Adachi, Norihiko Takeda and Mukund P. Sibi

Angew. Chem. Int. Ed.

Thiyl Radicals: From Simple Radical Additions to Asymmetric Catalysis

Hariharaputhiran Subramanian, Ramkumar Moorthy, Prof. Dr. Mukund P. Sibi

Org. Chem. Front.

Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

Gaoyuan Ma and Mukund P. Sibi

Adv. Synth. Catal.

Evaluating Thiourea Architecture for Intramolecular [2+2] Photocycloaddition of 4-Alkenylcoumarins

Nandini Vallavoju, Sermadurai Selvakumar, Steffen Jockusch, Manoj Thathamkulam Prabhakaran, Mukund P. Sibi, Jayaraman Sivqguru

Angew. Chem. Int. Ed.

Fluxionally chiral DMAP catalysts: kinetic resolution of axially chiral biaryl compounds

Gaoyuan Ma, Jun Deng and Mukund P. Sibi

Angew. Chem. Int. Ed.

Enantioselective Organo-Photocatalysis Mediated by Atropisomeric Thiourea Derivatives

Nandini Vallavoju, Dr. Sermadurai Selvakumar, Dr. Steffen Jockusch, Prof. Dr. Mukund P. Sibi, Prof. Dr. Jayaraman Sivaguru


Thermoset Coatings from Epoxidized Sucrose Soyate and Blocked, Bio-Based Dicarboxylic Acids

Dr. Curtiss S. Kovash Jr., Dr. Erin Pavlacky, Dr. Sermadurai Selvakumar, Prof. Mukund P. Sibi, Prof. Dean C. Webster


Regio- and Enantioselective Nitrone Cycloaddition to Alkynones for the Synthesis of Δ4-Isoxazolines

Mukund P. Sibi, Kelsey L. Dunkle and Digamber Rane

Green Chem.

Bio-based poly(vinyl ether)s and their application as alkyd-type surface coatings

Harjyoti Kalita, Sermadurai Selvakumar, Anurad Jayasiiriyamu, Shashi Fernando, Satyabrata Samanta, James Bahr, Samim Alam, Mukund Sibi, Jessica Void, Chad Ulven and Bret J. Chisholm


Angew. Chem. Int. Ed.

Csp3-F Bond Formation: A Free-Radical Approach

Prof. Dr. Mukund P. Sibi, Prof. Dr. Yannick Landais

Green Materials

Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T

Jie He, Satyabrata Samanta, Sermadurai Selvakumar, Jessica Lattimer, Chad Ulven, Mukund Sibi, James Bahr and Bret J. Chisholm


Polyamides based on the renewable monomer, 1,13-tridecane diamine II: Synthesis and characterization of nylon 13,6

Satyabrata Samanta, Jie He, Sermadurai Selvakumar, Jessica Lattimer,, Chad Ulven, Mukund Sibi, James Bahr and Bret J. Chisholm


Curr. Org. Synth.

Recent Advances in Nitrile Oxide Cycloadditions. Synthesis of Isoxazolines

Digamber Rane and Mukund Sibi



Enantioselective Diels-Alder Cycloadditions with β-Substituted Pyrazolidinone Propiolimides

Mukund P. Sibi, Wilfredo Cruz Jr. and Levi M. Stanley

Bull. Korean Chem. Soc.

3-isoxazolidinone: a new achiral template for enantioselective transformations

Mukund P. Sibi, Brandon Gustafson and Julien Coulomb

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