Cycloadditions. A powerful tool for the construction of quaternary stereocenters
Digamber Rane and Mukund P. Sibi
Org. Lett.
Nitrile Ylides: Diastereoselective Cycloadditions using Chiral Oxazolidinones Without Lewis Acid
Mukund P. Sibi, Takahiro Soeta and Craig P. Jasperse
Org. Lett.
Diels-Alder Cycloaddition Strategy for Kinetic Resolution of Chiral Pyrazolidinones
Mukund P. Sibi, Keisuke Kawashima and Levi M. Stanley
2008
Angew. Chem. Int. Ed.
Enantioselective enolate protonations: Friedel-Crafts reactions with α-substituted acrylates
Mukund P. Sibi, Julien Coulomb and Levi M. Stanley
Org. Lett.
Tin-Free Enantioselective Radical Reactions Using Silanes
Mukund P. Sibi, Yong-Hua Yang and Sunggi Lee
Synlett
Exo- and enantioselective Diels-Alder reactions: pyrazolidinone auxiliaries as a means to enhanced exo selectivity
Mukund P. Sibi, Xiaoping Nie, Jessica P. Shackleford, Levi M. Stanley and Frances Bouret
Chem. Biol. Drug Des.
Binding of matrix metalloproteinase inhibitors to extracellular matrix: 3D-QSAR analysis
Yufen Zhang, Viera Lukacova, Vladimir Bartus, Xiaoping Nie, Guorong Sun, Ethirajan Manivannan, Sandeep R. Ghorpade, Xiaomin Jin, Shankar Manyem, Mukund P. Sibi, Gregory R. Cook and Stefan Balaz
Copper(II)-Catalyzed Exo and Enantioselective Cycloadditions of Azomethine Imines
Mukund P. Sibi, Digamber Rane, Levi M. Stanley and Takahiro Soeta
Synlett
Chiral Lewis acid catalyzed enantioselective conjugate radical additions to α,β-unsaturated 2-pyridyl ketones
Mukund P. Sibi and Yong-Hua Yang
2007
Synlett
Diastereoselective conjugate radical additions to β-pyranones
Mukund P. Sibi and Arvin Yu
Angew. Chem. Int. Ed.
Enantioselective radical reactions: stereoselective aldol synthesis from cyclic ketones
Mukund P. Sibi and Sukanya Nad
J. Am. Chem. Soc.
Organocatalysis in Conjugate Amine Additions. Synthesis of β-Amino Acid Derivatives
Mukund P. Sibi and Kennosuke Itoh
Org. Lett.
Enantioselective 1,3-Dipolar Cycloadditions of Diazoacetates with Electron-Deficient Olefins
Mukund P. Sibi, Levi M. Stanley and Takahiro Soeta
J. Am. Chem. Soc.
Enantioselective Conjugate Addition of Hydrazines to α,β-Unsaturated Imides. Synthesis of Chiral Pyrazolidinones
Mukund P. Sibi and Takahiro Soeta
J. Am. Chem. Soc.
Organocatalysis in radical chemistry. enantioselective α-oxyamination of aldehydes
Mukund P. Sibi and Masayuki Hasegawa
Synlett
Enantioselective Diels-Alder reactions: effect of the achiral template on reactivity and selectivity
Mukund P. Sibi, Jianxie Chen and Levi Stanley
J. Am. Chem. Soc.
The Role of Achiral Pyrazolidinone Templates in Enantioselective Diels-Alder Reactions: Scope, Limitations, and Conformational Insights
Mukund P. Sibi, Levi M. Stanley, Xiaoping Nie, Lakshmanan Venkatraman, Mei Liu and Craig P. Jasperse
J. Comb. Chem.
Solution-Phase Parallel Synthesis of a Library of Δ2-Pyrazolines
Shankar Manyem, Mukund P. Sibi, Gerald H. Lushington, Benjamin Neunswander, Frank Schoenen and Jeffrey Aube
2006
Adv. Synth. Catal.
Enantioselective 1,3-dipolar cycloaddition of nitrile imines to α-substituted and α,β-disubstituted α,β-unsaturated carbonyl substrates: a method for synthesizing dihydropyrazoles bearing a chiral quaternary center
Mukund P. Sibi, Levi M. Stanley and Takahiro Soeta
J. Am. Chem. Soc.
Fluxional Additives: A Second Generation Control in Enantioselective Catalysis
Mukund P. Sibi, Shankar Manyem and Hector Palencia
J. Am. Chem. Soc.
Pyrones to Pyrans: Enantioselective Radical Additions to Acyloxy Pyrones
Mukund P. Sibi and Jake Zimmerman
Org. Lett.
Enantioselective Conjugate Radical Addition to α'-Hydroxy Enones
Sunggi Lee, Chae Jo Lim, Sunggak Kim, Rajesh Subramaniam, Jake Zimmerman and Mukund P. Sibi
Rad. Synth.
Enantioselective radical reactions
Jake Zimmerman and Mukund P. Sibi
Synlett
Enantioselective radical reactions: formation of chiral quaternary centers
Mukund P. Sibi and Liwen He
Tetrahedron
Enantioselective radical reactions. Evaluation of nitrogen protecting groups in the synthesis of β- Amino Acids
Mukund P. Sibi and Kalyani
2005
Sci. Synth.
Product class 7: β-Heteroatom-substituted alkanamides
S. Manyem and M. P. Sibi
Curr. Org. Chem.
Novel indole chemistry in the synthesis of heterocycles
Gordon W. Gribble, Mark G. Saulnier, Erin T. Pelkey, Tara L. S. Kishbaugh, Yanbing Liu, Jun Jiang, Hernando A; Trujillo, Daniel J. Keavy, Deborah A. Davis, Sam C. Conway, Frank L. Switzer, Sujata Roy, Richard A. Silva, Judy A. Obaza-Nutaitis, Mukund P. Sibi, Nikolai V. Moskalev, Timothy C. Barden, Louis Chang, Wendy M. Habeski (nee Simon), Benjamin Pelcman, William R. Sponholtz, III, Ryan W. Chau, Brett D. Allison, Sarah D. Garaas, Michael S. Sinha, Meredeth A. McGowan, Matthew R. Reese and Karen S. Harpp
Synthesis
Enantioselective radical methods for lactone synthesis: use of unprotected halo alcohols as radical precursors
Mukund P. Sibi and Miguel A. Guerrero
Org. Lett.
Stereoselective Conjugate Radical Additions: Application of a Fluorous Oxazolidinone Chiral Auxiliary for Efficient Tin Removal
Jason E. Hein, Jake Zimmerman, Mukund P. Sibi and Philip G. Hultin
Org. Lett.
Enantioselective Rhodium Enolate Protonations. A New Methodology for the Synthesis of β2-Amino Acids
Mukund P. Sibi, Hiroto Tatamidani and Kalyani Patil
J. Am. Chem. Soc.
An Entry to a Chiral Dihydropyrazole Scaffold: Enantioselective [3 + 2] Cycloaddition of Nitrile Imines
Mukund P. Sibi, Levi M. Stanley and Craig P. Jasperse
Org. Lett.
Enantioselective Cycloadditions with α,β-Disubstituted Acrylimides
Mukund P. Sibi, Zhihua Ma, Kennosuke Itoh, Narayanasamy Prabagaran and Craig P. Jasperse
J. Am. Chem. Soc.
Enantioselective Addition of Nitrones to Activated Cyclopropanes
Mukund P. Sibi, Zhihua Ma and Craig P. Jasperse
Org. Lett.
Enantioselective H-Atom Transfer Reaction: A Strategy to Synthesize Formaldehyde Aldol Products
Mukund P. Sibi and Kalyani Patil
J. Am. Chem. Soc.
Enantioselective Radical Addition/Trapping Reactions with α,β-Disubstituted Unsaturated Imides. Synthesis of anti-Propionate Aldols
Mukund P. Sibi, Goran Petrovic and Jake Zimmerman
2004
Synlett
Chiral relay in enantioselective conjugate radical additions using pyrazolidinone templates. How does metal geometry impact selectivity?
Mukund P. Sibi and Naranyanasamy Prabagaran
Tetrahedron Asymmetry
Enantioselective diethylzinc additions to aldehydes catalyzed by chiral relay ligands
Mukund P. Sibi and Levi M. Stanley
Tetrahedron Lett.
Enantioselective Diels-Alder reactions of 3-(acyloxy)acrylates
Mukund P. Sibi and Hirofumi Matsunaga
Synlett
An enantioselective total synthesis of (-)-stemoamide
Mukund P. Sibi and Thangaiah Subramanian
Org. Lett.
Application of Enantioselective Radical Reactions: Synthesis of (+)-Ricciocarpins A and B
Mukund P. Sibi and Liwen He
J. Am. Chem. Soc.
Chiral Lewis acid catalysis in nitrile oxide cycloadditions
Mukund P. Sibi, Kennosuke Itoh and Craig P. Jasperse
Eur. JOC
Synthesis of oxacycles by tandem radical addition-cyclization reactions
Enantioselective radical allylation reactions using chiral lanthanide Lewis acids
Mukund P. Sibi, Shankar Manyem and Rajesh Subramaniam
Angew. Chem. Int. Ed.
Enantioselective conjugate radical addition to β-acyloxy acrylate acceptors: An approach to acetate aldol-type products
Mukund P. Sibi, Jake Zimmerman and Tara Rheault
Tetrahedron Asymmetry
Enantioselective radical reactions: the use of metal triflimides as Lewis acids
Mukund P. Sibi and Goran Petrovic
J. Am. Chem. Soc.
Enantioselective Synthesis of α,β-Disubstituted-β-amino Acids
Mukund P. Sibi, Narayanasamy Prabagaran, Sandeep G. Ghorpade and Craig P. Jasperse
J. Am. Chem. Soc.
A New Class of Modular Chiral Ligands with Fluxional Groups
Mukund P. Sibi, Ruzhou Zhang and Shankar Manyem
Chem Rev.
Enantioselective Radical Processes
Mukund P. Sibi, Shankar Manyem and Jake Zimmerman
Org. Lett.
Tandem Radical Reactions and Ring-Closing Metathesis. Application in the Synthesis of Cyclooctenes
Mukund P. Sibi, Mona Aasmul, Hikaru Hasegawa and Thangaiah Subramanian
Prog. Org. Coat.
Determination of corrosion on aluminum alloy under protective coatings using fluorescent probes
Mukund P. Sibi and Zhengang Zong
2002
Chem. Eur. J.
Chiral relay: A novel strategy for the control and amplification of enantioselectivity in chiral Lewis acid promoted reactions
Oliver Corminboeuf, Laura Quaranta, Philippe Renaud, Mei Liu, Craig P. Jasperse and Mukund P. Sibi
Tetrahedron
Temperature dependent reversal of stereochemistry in enantioselective conjugate amine additions
Mukund P. Sibi, Uma Gorikunti and Mei Liu
Tetrahedron
Recent advances in the stereoselective synthesis of β-amino acids
Mei Liu and Mukund P. Sibi
Org. Lett.
Crotylations of α-Carbonyl Radicals with Crotylstannane
Mukund P. Sibi and Hideto Miyabe
Org. Lett.
An Efficient Method for Synthesis of Succinate-Based MMP Inhibitors
Mukund P. sibi and Hikaru Hasegawa
Org. Lett.
A Convenient Method for the Conversion of N-Acyloxazolidinones to Hydroxamic Acids
Mukund P. Sibi, Hikaru Hasegawa and Sandeep R. Ghorpade
Org. Lett.
Enantioselective Conjugate Addition of Silyl ketene Acetals to β-Enamidomalonates. Synthesis of β-Amino Acid Derivatives
Mukund P. Sibi and Jianxie Chen
Org. Lett.
Lanthanide Lewis Acid-Mediated Enantioselective Conjugate Radical Additions
Mukund P. Sibi and Shankar Manyem
J. Am. Chem. Soc.
Acyclic Diastereoselection in Prochiral Radical Addition to Prochiral Olefins
Mukund P. Sibi, Tara R. Rheault, Sithamali V. and Craig P. Jasperse
J. Am. Chem. Soc.
The Role of the Achiral Template in Enantioselective Transformations. Radical Conjugate Additions to α-Methacrylates Followed by Hydrogen Atom Transfer
Mukund P. Sibi and Justin B. Sausker
J. Org. Chem.
Free-radical-mediated conjugate additions. enantioselective synthesis of butyrolactone natural products: (-)-enterolactone, (-)-arctigenin, (-)-isoarctigenin, (-)-nephrosteranic acid, and (-)-roccellaric acid
Mukund P. Sibi, Pingrong Liu, Ji Jianguo,Saumen Hajra and Jian-xie Chen
2001
Can. J. Chem.
Enantioselective synthesis of peperomins A, C, D, and analogs - examination of diastereoselective cuprate conjugate additions to N-enoyl-4-diphenylmethyl-2-oxazolidinones
Mukund P. Sibi, Michael D. Johnson and T. Punniyamurthy
Org. Lett.
Enantioselective conjugate addition of hydroxylamines to pyrazolidinone acrylamides
Mukund P. Sibi and Mei Liu
Org. Lett.
Radical-Mediated Annulation Reactions. A Versatile Strategy for the Preparation of a Series of Carbocycles
Mukund P. Sibi, Jianxie Chen and Tara R. Rheault
Chem.
Highly diastereoselective radical addition-cyclization strategy: facile synthesis of substituted furans
Mukund P. Sibi, Tara R. Rheault, Hideta Miyabe, Kalyani Patil and Craig P. Jasperse
J. Am. Chem. Soc.
Enantioselective conjugate addition of organomagnesium amides to enamidomalonates: synthesis of either enantiomer of β-amino acid derivatives
Mukund P. Sibi and Yasutomi Asano
J. Am. Chem. Soc.
Enantioselective Tandem Radical Reactions: Vicinal Difunctionalization in Acyclic Systems with Control over Relative and Absolute Stereochemistry
Mukund P. Sibi and Jianxie Chen
J. Am. Chem. Soc.
A new approach to enantiocontrol and enantioselectivity amplification: chiral relay in Diels-Alder reactions
Mukund P. Sibi, Lakshmanan Venkatraman , Mei Liu and Craig P. Jasperse
Curr. Org. Chem.
Reversal of stereochemistry in enantioselective transformations. Can they be planned or are they just accidental?
Mukund P. Sibi and Mei Liu
Angew. Chem. Int. Ed.
Enantioselective hydrogen atom transfer reactions: synthesis of N-acyl-α-amino acid esters
Mukund P. Sibi, Yasutomi Asano and Justin B. Sausker
2000
Org. Lett.
N-Benzylhydroxylamine Addition to β-Aryl Enoates. Enantioselective Synthesis of β-Aryl-β-amino Acid Precursors
Mukund P. Sibi and Mei Liu
J. Am. Chem. Soc.
Higher Selectivity at Higher Temperatures! Effect of Precursor Stereochemistry on Diastereoselectivity in Radical Allylations. Insight into the Role of the Lewis Acid
Mukund P. Sibi and Tara R. Rheault
Can. J. Chem.
A short synthesis of both enantiomers of enterolactone
Mukund P. Sibi, Pingrong Liu and Michael D. Johnson
